baricitinib
Baricitinib was approved in February of 2017 as a second-line orally administered treatment for moderate to severe active rheumatoid arthritis in adults, either as a monotherapy or when combined with methotrexate.Baricitinib is a selective and reversible Janus kinase 1 (JAK1) and 2 (JAK2) inhibitor. Janus kinases belong to the tyrosine protein kinase family and play an important role in the proinflammatory pathway signalling that is frequently over-activated in autoimmune disorders such as rheumatoid arthritis. Reference standards of Baricitinib API, and its pharmacopeial, non pharmacopeial impurities, and stable isotopes are listed below.
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[pname] => Baricitinib
[catalogue_number] => PA 29 41000
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[weight] => 371.42
[form] => C16H17N7O2S
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Catalogue No.:PA 29 41000
Molecular Formula : C16H17N7O2S
Molecular Weight : 371.42
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[pname] => 2-(1-(Ethylsulfonyl)-3-(4-(7-(hydroxymethyl)-7H-pyrrolo[2,3-d]pyrimidin-4-yl)-1H-pyrazol-1-yl)azetidin-3-yl)acetonitrile
[catalogue_number] => PA 29 0411001
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2-(1-(Ethylsulfonyl)-3-(4-(7-(hydroxymethyl)-7H-pyrrolo[2,3-d]pyrimidin-4-yl)-1H-pyrazol-1-yl)azetidin-3-yl)acetonitrile
Catalogue No.:PA 29 0411001
Molecular Formula : C17H19N7O3S
Molecular Weight : 401.45
stdClass Object
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2-(1-(Ethylsulfonyl)-3-(4-(7-((2-(trimethylsilyl)ethoxy)methyl)-7H-pyrrolo[2,3-d]pyrimidin-4-yl)-1H-pyrazol-1-yl)azetidin-3-yl)acetonitrile
Catalogue No.:PA 29 0411002
Molecular Formula : C22H31N7O3SSi
Molecular Weight : 501.68
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[pname] => N-((3-(4-(7H-Pyrrolo[2,3-d]pyrimidin-4-yl)-1H-pyrazol-1-yl)-5-oxotetrahydrofuran-3-yl)methyl)ethanesulfonamide
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N-((3-(4-(7H-Pyrrolo[2,3-d]pyrimidin-4-yl)-1H-pyrazol-1-yl)-5-oxotetrahydrofuran-3-yl)methyl)ethanesulfonamide
Catalogue No.:PA 29 0411003
Molecular Formula : C16H18N6O4S
Molecular Weight : 390.42
stdClass Object
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2-(3-(4-(7H-Pyrrolo[2,3-d]pyrimidin-4-yl)-1H-pyrazol-1-yl)-1-(ethylsulfonyl)azetidin-3-yl)acetic acid
Catalogue No.:PA 29 0411004
Molecular Formula : C16H18N6O4S
Molecular Weight : 390.42
stdClass Object
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2-(3-(4-(7H-Pyrrolo[2,3-d]pyrimidin-4-yl)-1H-pyrazol-1-yl)-1-(propylsulfonyl)azetidin-3-yl)acetonitrile
Catalogue No.:PA 29 0411005
Molecular Formula : C17H19N7O2S
Molecular Weight : 385.45
stdClass Object
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[pname] => Tert-butyl 3-(4-(7H-pyrrolo[2,3-d]pyrimidin-4-yl)-1H-pyrazol-1-yl)-3-(cyanomethyl)azetidine-1-carboxylate
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Tert-butyl 3-(4-(7H-pyrrolo[2,3-d]pyrimidin-4-yl)-1H-pyrazol-1-yl)-3-(cyanomethyl)azetidine-1-carboxylate
Catalogue No.:PA 29 0411006
Molecular Formula : C19H21N7O2
Molecular Weight : 379.42
stdClass Object
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[pname] => 2-(3-(4-(7H-Pyrrolo[2,3-d]pyrimidin-4-yl)-1H-pyrazol-1-yl)azetidin-3-yl)acetonitrile Dihydrochloride
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2-(3-(4-(7H-Pyrrolo[2,3-d]pyrimidin-4-yl)-1H-pyrazol-1-yl)azetidin-3-yl)acetonitrile Dihydrochloride
Catalogue No.:PA 29 0411007
Molecular Formula : C14H15Cl2N7
Molecular Weight : 352.22
stdClass Object
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[pname] => Methyl 2-(3-(4-(7H-pyrrolo[2,3-d]pyrimidin-4-yl)-1H-pyrazol-1-yl)-1-(ethylsulfonyl)azetidin-3-yl)acetate
[catalogue_number] => PA 29 0411008
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[weight] => 404.45
[form] => C17H20N6O4S
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Methyl 2-(3-(4-(7H-pyrrolo[2,3-d]pyrimidin-4-yl)-1H-pyrazol-1-yl)-1-(ethylsulfonyl)azetidin-3-yl)acetate
Catalogue No.:PA 29 0411008
Molecular Formula : C17H20N6O4S
Molecular Weight : 404.45
stdClass Object
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[catalogue_number] => PA 29 0411009
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[weight] => 400.42
[form] => C16H16N8O3S
[cas] => NA
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2-(1-(Ethylsulfonyl)-3-(4-(7-nitroso-7H-pyrrolo[2,3-d]pyrimidin-4-yl)-1H-pyrazol-1-yl)azetidin-3-yl)acetonitrile
Catalogue No.:PA 29 0411009
Molecular Formula : C16H16N8O3S
Molecular Weight : 400.42
stdClass Object
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[form] => C10H14N4O2S
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2-(1-(Ethylsulfonyl)-3-(1H-pyrazol-1-yl)azetidin-3-yl)acetonitrile
Catalogue No.:PA 29 0411010
Molecular Formula : C10H14N4O2S
Molecular Weight : 254.31
stdClass Object
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[weight] => 488.53
[form] => C22H20N10O2S
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2-(3-(4-(7H-[4,7'-Bipyrrolo[2,3-d]pyrimidin]-4'-yl)-1H-pyrazol-1-yl)-1-(ethylsulfonyl)azetidin-3-yl)acetonitrile
Catalogue No.:PA 29 0411011
Molecular Formula : C22H20N10O2S
Molecular Weight : 488.53
stdClass Object
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[weight] => 506.6
[form] => C20H26N8O4S2
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2,2'-(1H,1'H-[4,4'-Bipyrazole]-1,1'-diylbis(1-(ethylsulfonyl)azetidine-3,3-diyl))diacetonitrile
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[catalogue_number] => PA 29 0411014
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[weight] => 471.54
[form] => C21H25N7O4S
[cas] => 2055723-13-0
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Tert-butyl 4-(1-(3-(cyanomethyl)-1-(ethylsulfonyl)azetidin-3-yl)-1H-pyrazol-4-yl)-7H-pyrrolo[2,3-d]pyrimidine-7-carboxylate
Catalogue No.:PA 29 0411014
Molecular Formula : C21H25N7O4S
Molecular Weight : 471.54
stdClass Object
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[pname] => 4-Chloro-7-nitroso-7H-pyrrolo[2,3-d]pyrimidine
[catalogue_number] => PA 29 0411015
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[weight] => 182.57
[form] => C6H3ClN4O
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4-Chloro-7-nitroso-7H-pyrrolo[2,3-d]pyrimidine
Catalogue No.:PA 29 0411015
Molecular Formula : C6H3ClN4O
Molecular Weight : 182.57
stdClass Object
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[catalogue_number] => PA 29 0411016
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[weight] => 175.97
[form] => C3H2BrN3O
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4-Bromo-1-nitroso-1H-pyrazole
Catalogue No.:PA 29 0411016
Molecular Formula : C3H2BrN3O
Molecular Weight : 175.97
stdClass Object
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[weight] => 266.15
[form] => C13H23BN2O3
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1-(1-Ethoxyethyl)-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrazole
Catalogue No.:PA 29 0411017
Molecular Formula : C13H23BN2O3
Molecular Weight : 266.15
stdClass Object
(
[pname] => tert-Butyl 3-(cyanomethyl)-3-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrazol-1-yl)azetidine-1-carboxylate
[catalogue_number] => PA 29 0411018
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[weight] => 388.28
[form] => C19H29BN4O4
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tert-Butyl 3-(cyanomethyl)-3-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrazol-1-yl)azetidine-1-carboxylate
Catalogue No.:PA 29 0411018
Molecular Formula : C19H29BN4O4
Molecular Weight : 388.28
stdClass Object
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[weight] => 393.45
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(4-(1-(3-(Cyanomethyl)azetidin-3-yl)-1H-pyrazol-4-yl)-7H-pyrrolo[2,3-d]pyrimidin-7-yl)methyl Pivalate
Catalogue No.:PA 29 0411019
Molecular Formula : C20H23N7O2
Molecular Weight : 393.45
stdClass Object
(
[pname] => (4-(1-(3-(Cyanomethyl)-1-(ethylsulfonyl)azetidin-3-yl)-1H-pyrazol-4-yl)-7H-pyrrolo[2,3-d]pyrimidin-7-yl)methyl Pivalate
[catalogue_number] => PA 29 0411020
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[weight] => 485.56
[form] => C22H27N7O4S
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(4-(1-(3-(Cyanomethyl)-1-(ethylsulfonyl)azetidin-3-yl)-1H-pyrazol-4-yl)-7H-pyrrolo[2,3-d]pyrimidin-7-yl)methyl Pivalate
Catalogue No.:PA 29 0411020
Molecular Formula : C22H27N7O4S
Molecular Weight : 485.56
stdClass Object
(
[pname] => 1-Boc-3-(cyanomethylene)azetidine
[catalogue_number] => PA 29 0411021
[category_ids] => ,70,75,78,79,82,
[chemical_name] =>
[weight] => 194.23
[form] => C10H14N2O2
[cas] => 1153949-11-1
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1-Boc-3-(cyanomethylene)azetidine
Catalogue No.:PA 29 0411021
Molecular Formula : C10H14N2O2
Molecular Weight : 194.23
stdClass Object
(
[pname] => 2-(3-(4-(1-(3-(Cyanomethyl)-1-(ethylsulfonyl)azetidin-3-yl)-1H-pyrazol-4-yl)-7H-pyrrolo[2,3-d]pyrimidin-7-yl)-1-(ethylsulfonyl)azetidin-3-yl)acetonitrile
[catalogue_number] => PA 29 0411022
[category_ids] => ,75,76,78,70,82,
[chemical_name] =>
[weight] => 557.65
[form] => C23H27N9O4S2
[cas] => 2402776-84-3
[pslug] => 2402776-84-3-2-3-4-1-3-cyanomethyl-1-ethylsulfonyl-azetidin-3-yl-1h-pyrazol-4-yl-7h-pyrrolo-2-3-d-pyrimidin-7-yl-1-ethylsulfonyl-azetidin-3-yl-acetonitrile-pa290411022
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2-(3-(4-(1-(3-(Cyanomethyl)-1-(ethylsulfonyl)azetidin-3-yl)-1H-pyrazol-4-yl)-7H-pyrrolo[2,3-d]pyrimidin-7-yl)-1-(ethylsulfonyl)azetidin-3-yl)acetonitrile
Catalogue No.:PA 29 0411022
Molecular Formula : C23H27N9O4S2
Molecular Weight : 557.65
stdClass Object
(
[pname] => tert-Butyl 3-(cyanomethyl)-3-(4-(7-((pivaloyloxy)methyl)-7H-pyrrolo[2,3-d]pyrimidin-4-yl)-1H-pyrazol-1-yl)azetidine-1-carboxylate
[catalogue_number] => PA 29 0411023
[category_ids] => ,71,81,78,70,82,
[chemical_name] =>
[weight] => 493.57
[form] => C25H31N7O4
[cas] => 2102104-37-8
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tert-Butyl 3-(cyanomethyl)-3-(4-(7-((pivaloyloxy)methyl)-7H-pyrrolo[2,3-d]pyrimidin-4-yl)-1H-pyrazol-1-yl)azetidine-1-carboxylate
Catalogue No.:PA 29 0411023
Molecular Formula : C25H31N7O4
Molecular Weight : 493.57
stdClass Object
(
[pname] => 4-Chloro-7-((2-(trimethylsilyl)ethoxy)methyl)-7H-pyrrolo[2,3-d]pyrimidine
[catalogue_number] => PA 29 0411024
[category_ids] => ,78,70,82,88,
[chemical_name] =>
[weight] => 283.83
[form] => C12H18ClN3OSi
[cas] => 941685-26-3
[pslug] => 941685-26-3-4-chloro-7-2-trimethylsilyl-ethoxy-methyl-7h-pyrrolo-2-3-d-pyrimidine-pa290411024
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4-Chloro-7-((2-(trimethylsilyl)ethoxy)methyl)-7H-pyrrolo[2,3-d]pyrimidine
Catalogue No.:PA 29 0411024
Molecular Formula : C12H18ClN3OSi
Molecular Weight : 283.83
stdClass Object
(
[pname] => 2-(3-(4-(7H-Pyrrolo[2,3-d]pyrimidin-4-yl)-1H-pyrazol-1-yl)-1-nitrosoazetidin-3-yl)acetonitrile
[catalogue_number] => PA 29 0411025
[category_ids] => ,78,70,82,162,
[chemical_name] =>
[weight] => 308.31
[form] => C14H12N8O
[cas] => NA
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2-(3-(4-(7H-Pyrrolo[2,3-d]pyrimidin-4-yl)-1H-pyrazol-1-yl)-1-nitrosoazetidin-3-yl)acetonitrile
Catalogue No.:PA 29 0411025
Molecular Formula : C14H12N8O
Molecular Weight : 308.31
stdClass Object
(
[pname] => (1-(1-Ethoxyethyl)-1H-pyrazol-4-yl)boronic Acid
[catalogue_number] => PA 29 0411026
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[chemical_name] =>
[weight] => 184
[form] => C7H13BN2O3
[cas] => 2227194-01-4
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(1-(1-Ethoxyethyl)-1H-pyrazol-4-yl)boronic Acid
stdClass Object
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[pname] => 4-(1-(3-(Cyanomethyl)-1-(ethylsulfonyl)azetidin-3-yl)-1H-pyrazol-4-yl)pyrimidine-5-carbonitrile
[catalogue_number] => PA 29 0411028
[category_ids] => ,78,70,82,
[chemical_name] =>
[weight] => 357.39
[form] => C15H15N7O2S
[cas] => 2964606-44-6
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4-(1-(3-(Cyanomethyl)-1-(ethylsulfonyl)azetidin-3-yl)-1H-pyrazol-4-yl)pyrimidine-5-carbonitrile
Catalogue No.:PA 29 0411028
Molecular Formula : C15H15N7O2S
Molecular Weight : 357.39
stdClass Object
(
[pname] => 2-(1-(Ethylsulfonyl)-3-(4-(5-(hydroxymethyl)-7H-pyrrolo[2,3-d]pyrimidin-4-yl)-1H-pyrazol-1-yl)azetidin-3-yl)acetonitrile
[catalogue_number] => PA 29 0411029
[category_ids] => ,78,70,82,
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[weight] => 401.45
[form] => C17H19N7O3S
[cas] => NA
[pslug] => 2-1-ethylsulfonyl-3-4-5-hydroxymethyl-7h-pyrrolo-2-3-d-pyrimidin-4-yl-1h-pyrazol-1-yl-azetidin-3-yl-acetonitrile-pa290411029
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2-(1-(Ethylsulfonyl)-3-(4-(5-(hydroxymethyl)-7H-pyrrolo[2,3-d]pyrimidin-4-yl)-1H-pyrazol-1-yl)azetidin-3-yl)acetonitrile
Catalogue No.:PA 29 0411029
Molecular Formula : C17H19N7O3S
Molecular Weight : 401.45
stdClass Object
(
[pname] => 2-(3-(4-(7-Nitroso-7H-pyrrolo[2,3-d]pyrimidin-4-yl)-1H-pyrazol-1-yl)-1-(propylsulfonyl)azetidin-3-yl)acetonitrile
[catalogue_number] => PA 29 0411030
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[weight] => 414.44
[form] => C17H18N8O3S
[cas] => NA
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2-(3-(4-(7-Nitroso-7H-pyrrolo[2,3-d]pyrimidin-4-yl)-1H-pyrazol-1-yl)-1-(propylsulfonyl)azetidin-3-yl)acetonitrile
Catalogue No.:PA 29 0411030
Molecular Formula : C17H18N8O3S
Molecular Weight : 414.44
stdClass Object
(
[pname] => 4-(1H-Pyrazol-4-yl)-7-(((2-(trimethylsilyl)ethoxy)methoxy)methyl)-7H-pyrrolo[2,3-d]pyrimidine
[catalogue_number] => PA 29 0411033
[category_ids] => ,78,70,82,88,
[chemical_name] =>
[weight] => 345.48
[form] => C16H23N5O2Si
[cas] => NA
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4-(1H-Pyrazol-4-yl)-7-(((2-(trimethylsilyl)ethoxy)methoxy)methyl)-7H-pyrrolo[2,3-d]pyrimidine
Catalogue No.:PA 29 0411033
Molecular Formula : C16H23N5O2Si
Molecular Weight : 345.48
